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resume pfliederer ru WO 2004104095 A1. BLOCK COPOLYMER COMPOSITION AND TRANSPARENT ELASTOMERIC ARTICLES PRODUCED THEREFROM. CROSS REFERENCE STATEMENT This application claims the benefit of U.S. Provisional Application No. Improving? 60/470,461, filed May 14, 2003. The present invention relates to Service print, compositions of monovinylidene aromatic- conjugated diene block copolymers.
BACKGROUND Elastomeric articles produced from thermoplastic elastomers such as block copolymers are well known. Thermoplastic elastomers, such as copolymers having blocks of monovinylidene aromatic monomer and entrance essays, conjugated diene monomer are often blended with other thermoplastic polymers, for example, polypropylene, polystyrene, polyethylene, or ethylene vinyl acetate copolymers, to improve processing. These thermoplastic polymers tend to reduce the viscosity of the Service print elastomers and provide improved processability by reducing the elastic nature of the composition, as described in U.S. Patents 4,329,309; 4,173,612; 4,305,990; 4,977,014; and 6,410,129 B2, the teachings of which are incorporated herein by reference. Typically, the elastomeric block copolymer is compounded with a thermoplastic polymer and fed to an extruder to produce film, fiber or netting materials. However, this process is expensive due to the amount of scrap material generated, and the potential of low quality or non-homogeneity of the product.
Further, it is also known in the art that blends of elastomeric block copolymer and thermoplastic polymers can be directly fed to converting extruders to produce useful articles. However, this process requires feeding systems to accommodate multiple components, and the potential for low quality or non-homogeneity of the converted article remains. An additional disadvantage of the compositions discussed above includes the production of opaque or hazy products (that is, low transparency) due to significant differences in the refractive indices of the polymers. Therefore, what is needed is a transparent block copolymer or blend composition that can be converted into a useful transparent elastomeric article. Further, what is needed is a blended product of an elastomeric block copolymer and a thermoplastic block copolymer that can be produced in the same polymerization process, blended while in solution and produced as a single pellet product, eliminating the need for compounding or direct feed of improving college multiple components to an extruder.
The present invention is an elastomeric polymer blend composition comprising: A) from 65 to 92 parts by weight of at least one monovinylidene aromatic-conjugated diene block copolymer, hereafter referred to as elastomeric block copolymer, having a monovinylidene aromatic content of less than 50 weight percent, based on runner essays relationship, the total weight of the elastomeric block copolymer and a weight average molecular weight (Mw) of from 50,000 to 400,000; B) from 8 to 35 parts by weight of at least one monovinylidene aromatic-conjugated diene copolymer, hereafter referred to as thermoplastic block copolymer, having a monovinylidene aromatic content of 50 weight percent or more, based on the total weight of the improving college essays thermoplastic block copolymer and a weight average molecular weight of from 50,000 to 300,000; and inspiration my paper, C) from 0 to improving college entrance essays, 30 parts by my paper, weight of an extender oil, based on the total weight of A, B and C. The elastomeric polymer blend composition may be used in the production of, for example, a monolayer film, as the major component in a coextruded structure such as a multilayer film, an injection molded part, an extruded profile such as tubing, a monolayer or multi-component fiber, and/or a non-woven article. The elastomeric articles exhibit outstanding elastic and stress relaxation properties. DETAILED DESCRIPTION. Unless otherwise stated, each number range, such as from 8 to improving college, 35 parts by weight, includes both endpoints of the range. The present invention relates to a low stress relaxation transparent elastomeric polymer blend comprising at least one elastomeric block copolymer and at inspiration my paper least one thermoplastic block copolymer. Improving College? Each elastomeric block copolymer comprises an elastomeric soft block portion and at least two thermoplastic hard block portions. Each thermoplastic block copolymer comprises at least one elastomeric soft block portion and at least one thermoplastic hard block portion. As used herein, the term stress relaxation refers to the percentage loss of tension or load between the maximum load or force encountered after elongating an elastomeric material at a specific rate of extension to to write my paper, a predetermined length (or the load or force measured at some initial length) and the remaining load or force measured after the sample has been held at that length or elongation for a specified period of time. Improving Essays? Relaxation is expressed as percentage loss of the initial load encountered at a specific extension of an elastomeric material.
As used herein, the terms transparency or highly transparent refers to Stakeholders, a greater than 75 percent (%) value for college entrance essays total transmission. Haze and total transmission (that is, transparency) are measured using the HunterLab Colorquest XE spectrophotometer which uses d/0° (sphere) geometry for transmission measurements. While this haze measurement does not conform to ASTM method D 1003, Standard Test Method for Haze and Luminous Transmittance of or after table Transparent Plastics, due to differences in instrument geometry, values obtained for certified standards are similar. Haze is equal to the percent of diffuse transmittance relative to the total transmittance of the incident light, where diffuse transmittance is measured from the light forward scattered at angles greater than 2.5°. As used herein, the terms elastic or elastomeric refer to any material which is college essays capable of being elongated or deformed under an following externally applied force, and which will substantially resume its original dimension or shape, sustaining only small permanent set (typically no more than about 20 percent), after the external force is released. The term elastomer refers to any material exhibiting elastic properties. As used herein, the term elastomeric block copolymer refers to a block copolymer that contains less than 50 weight percent (wt%) and more preferably less than 35 wt% monovinylidene aromatic monomer in the block copolymer, based on the total weight of the improving college block copolymer. As used herein, the term thermoplastic block copolymer refers to a block copolymer that contains 50 wt% or more, and more preferably 65 wt% or more, of a monovinylidene aromatic monomer in the block copolymer, based on blue, the total weight of the block copolymer. The elastomeric and thermoplastic block copolymers are produced from monovinylidene aromatic monomers and conjugated diene monomers. Monovinylidene aromatic monomers suitable for college essays use in preparing the block copolymers include, but are not limited to, monovinylidene aromatic monomers described in U.S. Patents 4,666,987, 4,572,819 and 4,585,825, and 5,721,320 which are incorporated by runner relationship, reference herein.
Preferably, the monovinylidene aromatic monomers are selected from styrene, alpha- methylstyrene, vinyltoluenes, and vinylpyridines. Conjugated diene monomers include, but are not limited to 1,3-butadiene, isoprene, chloroprene, and improving entrance essays, 1,3-pentadiene. Preferred monomers are styrene, 1,3-butadiene and isoprene. In a preferred embodiment, the block copolymers are styrenic block copolymers or styrene-diene block copolymers, such as styrene-butadiene (SB), styrene-butadiene-styrene (SBS), styrene-isoprene (SI), styrene-isoprene-styrene (SIS), SISIS, and Stakeholders, SBSBS. Alternatively, the entrance essays monovinylidene aromatic blocks may be different such as in a styrene- diene-alphamethylstyrene block copolymer, or the diene blocks may be different such as in a styrene-isoprene-styrene-butadiene-styrene (SISBS) block copolymer. The block copolymers may be linear or branched, having from 2 to Stakeholders, 7 blocks.
However, the college essays block copolymers are preferably linear triblock copolymers, such as SBS and SIS. Most preferably, both the elastomeric and thermoplastic block copolymers are SIS block copolymers. Stakeholders? The block copolymers may also be tapered, wherein there is a gradual compositional transition from one block to another rather than an abrupt change, as is well known in the art. The elastomeric block copolymer used in the polymer blend composition of the present invention typically corresponds to one of the following formulas: A-B-R(-B-A) n Formula I or A-(BA-) X -BA Formula ? wherein: each A is independently, that is, each A may be the same or different, a polymer block comprising a monovinylidene aromatic monomer and each B is independently, that is, each B may be the same or different, a polymer block comprising a conjugated diene and optionally a monovinylidene aromatic monomer, R is the remnant of a multifunctional coupling agent, n is an integer from 1 to 5, and x is a real number from 0 to 4. In Formula I, n is college entrance essays preferably 1 to 3 and more preferably 1. In Formula ?, x is preferably an integer of from 0 to 2, and more preferably 0. At least 50 wt% or more of the elastomeric block copolymer is conjugated diene, based on the total weight of the elastomeric block copolymer. The conjugated diene may comprise a single conjugated diene or mixture of thesis of contents more than one conjugated diene such as a mixture of isoprene and butadiene.
The monovinylidene aromatic block of the elastomeric block copolymer is less than 50 wt% and is typically from 8, preferably from 10, more preferably from 12, and improving college entrance, most preferably from 15 wt% to less than 50, preferably less than () 45, more preferably 40 and most preferably 35 wt%, based on the total weight of the elastomeric block copolymer. The elastomeric block copolymer typically has a Mw in the range of my paper 50,000 to 400,000 Daltons. Essays? As used herein, all Mw's are expressed in Daltons, which is equivalent to grams/mole (g/mol). In linear elastomeric block copolymers, each monovinylidene aromatic monomer block preferably has a peak Mw of at thesis before of contents least ( ) 9,000, more preferably 9,500 and most preferably 10,000. Preferably, each monovinylidene aromatic monomer block has a peak Mw of 62,000 or less (), more preferably 53,000, and most preferably 44,000. Each block may have its' own individual Mw. In other words, each monovinylidene aromatic monomer block within the elastomeric block copolymer does not necessarily have to be the same Mw. Improving Essays? Copolymers where the r project monovinylidene aromatic monomer blocks are not the same Mw are typically referred to improving entrance, as asymmetrical. Before Of Contents? Preferably, each conjugated diene block has a peak Mw of 40,000, more preferably 50,000 and improving college essays, most preferably 60,000 to Stakeholders, 200,000, more preferably to 175,000, and most preferably to 150,000.
In one embodiment, the elastomeric block copolymer is in radial form, as represented by Formula I, and each monovinylidene aromatic block has a peak Mw of. 9,000, more preferably 9,500, and most preferably 10,000 to 32,000, more preferably to 27,000 and improving college entrance, most preferably to 22,000. Preferably, each conjugated diene block has a peak Mw of 31 ,000, more preferably 38,000 and my paper, most preferably 41 ,000 to 86,000, more preferably to 84,000 and entrance essays, most preferably to 81,000. Preferably, the radial elastomeric block copolymer has a peak Mw of 135,000, more preferably 140,000 and even more preferably 145,000 to 400,000, more preferably to 375,000 and even more preferably to 350,000. In one embodiment, the elastomeric block copolymer has a refractive index in the' range from 1.5240 to 1.5526, preferably from 1.5256 to 1.5492, more preferably in the range from 1.5269 to 1.5458, and Service, most preferably from college essays, 1.5289 to 1.5424. Refractive index is measured using pressed films less than 0.020 inches (0.05 cm) thick using an Abbe-type refractometer at 25° C according to ASTM Standard D-542. The thermoplastic block copolymer useful in the polymer blend composition of the present invention typically correspond to Formulas I and II as stated previously. In addition, the thermoplastic block copolymer can correspond to Formula HI: B y -(AB-) Z -AB Formula HI wherein A and the kite relationship, B are as defined previously, y is improving entrance essays 0 or 1 , and z is a real number from thesis abstract before of contents, 0 to 4. However, less than 50 wt% of the thermoplastic block copolymer is a conjugated diene, based on the total weight of the college thermoplastic block copolymer.
The conjugated diene may comprise a single conjugated diene or mixture of conjugated dienes such as a mixture of isoprene and butadiene. The monovinylidene aromatic block of the thermoplastic block copolymer is 50 wt%, more preferably 60, and the kite runner essays father/son, most preferably 65 wt% to 95, more preferably to 90, and most preferably to 85 wt%, based on college entrance essays, the total weight of the thermoplastic block copolymer. The thermoplastic block copolymer typically has a Mw in the range of Service blue 50,000 Daltons to improving college entrance essays, 300,000 Daltons. In linear thermoplastic block copolymers, each monovinylidene aromatic monomer block of the thermoplastic block copolymer has a peak Mw that is desirably 12,500, preferably? 14,000, more preferably 16,250 and most preferably 18,750. Each monovinylidene aromatic monomer block has a peak Mw that is desirably 250,000, preferably 225,000, more preferably 200,000 and most preferably 175,000. If the thermoplastic block copolymer comprises more than one monovinylidene aromatic monomer block, then each block may have its' own individual Mw. Each conjugated diene block of a linear thermoplastic block copolymer has a peak Mw that is preferably 5,000, more preferably? 10,000 and most preferably 15,000 to 125,000, more preferably to essays father/son, 120,000, and most preferably to 115,000.
In one embodiment, diblock structures as derived in Formula IE are useful thermoplastic block copolymers. In this case, each conjugated diene block has a peak Mw of ? 2,500, more preferably ? 7,000 and most preferably 12,000 to 150,000, more preferably to improving college essays, 100,000, and most preferably to 50,000. In another embodiment, the thermoplastic block copolymer is in radial form, corresponding to Formula I. In this embodiment, each monovinylidene aromatic block has a peak Mw that is Service blue preferably 7,400, more preferably 8,800, and most preferably 11 ,700 to 83,800, more preferably to 80,000, and most preferably to 78,000. Entrance? Each conjugated diene block of a radial thermoplastic block copolymer has a peak Mw that is preferably 700 or more, more preferably 2,000 and most preferably 3,000 to 45,000, more preferably to. 40,000, and most preferably to 155,000. Blue? The radial thermoplastic block copolymer has a peak Mw that is preferably 50,000, more preferably 70,000 and entrance essays, even more preferably 80,000 to 300,000, more preferably to statement, 280,000, and entrance, even more preferably to Stakeholders, 260,000. Improving Entrance Essays? In one embodiment, the abstract before or after table of contents thermoplastic block copolymer has a refractive index that ranges from 1.5526 to 1.5925, preferably from 1.5624 to 1.5882, more preferably from. 1.5667 to 1.5839, and improving college entrance essays, most preferably from 1.5753 to 1.5796. Other related copolymers and statistics, methods of producing the same are disclosed in U.S.
Patent Nos. 4,086,298, 4,167,545, 4,335,221, 4,418,180, 4,180,530, 4,221,884, 4,346,198, 4,248,980, 4,248,981, 4,248,982, 4,248,983, and 4,248,984, the disclosures of which are hereby incorporated by reference. The elastomeric and thermoplastic block copolymers can be prepared by anionic polymerization. For purposes of the present specification, the phrase living polymer refers to a polymer being produced as it exists during an anionic polymerization process. Examples of sequential polymerization processes that result in living block polymers after completion of polymerization are known in the prior art and include US 5,242,984 and improving entrance essays, US.
5,750,623 the teachings of which are incorporated herein by reference; and in Holden et. al., Thermoplastic Elastomers, 2nd Edition; pages 51-53, 1996. Alkali metal hydrocarbon initiators suitable for anionic polymerization are well known in the art and such initiators include, but are not limited to, lithium alkyls, sodium alkyls, and potassium alkyls. Abstract Before Or After Table Of Contents? Preferred initiators are lithium alkyls, such as sec-butyllithium and n-butyllithium. Solvents or diluents suitable for the anionic polymerization are also well known in college essays, the art.
Examples included aromatic hydrocarbons, saturated aliphatic hydrocarbons, saturated cycloaliphatic hydrocarbons, linear ethers and cyclic ethers, and mixtures thereof. Preferred solvents or diluents are cyclohexane, n-hexane, and inspiration, isopentane, and mixtures thereof. The polymer blend of the present invention typically comprises from 65 wt%, preferably from 70 wt%, more preferably from 72 wt%, and most preferably from essays, 75 to 92 wt%, preferably to 90 wt%, more preferably to 85 wt% and most preferably to 80 wt% of elastomeric block copolymer A, based on the total weight of A, B and C, each of which is statement defined herein. The amount of thermoplastic block copolymer B used in the polymer blend composition of the improving present invention depends upon the article produced and the method of producing the the kite runner article. One skilled in the art would recognize the necessary properties that the composition of the invention must have to allow the composition to college essays, be processed by the chosen method. For example, films may be cast wherein as little as 8 parts by weight (pbw) of runner relationship thermoplastic block copolymer is used, whereas, at improving college least 15 pbw of the thermoplastic block copolymer is preferably used to prepare films by extrusion blowing methods or in the production of fibers and non- oven structures. In injection molded and profile extruded applications, the Stakeholders composition would likely be at least 15 pbw and up to 35 pbw of thermoplastic block copolymer, based on the combined weights of A, B and C.
The polymer blend of the present invention typically comprises from 8 wt%, preferably from 10 wt%, more preferably from 12 wt%, and most preferably from 14 wt% to college essays, 35 wt%, preferably to 32 wt%, more preferably to 30 wt% and most preferably to 25 wt% of the thermoplastic block copolymer B, based on the total weight of A, B and C. If a blend of elastomeric block copolymers, such as a SIS block copolymer and a SBS block copolymer is r project statistics desired, the SIS block copolymer is preferably present in an amount of 50 wt%, more preferably 60 wt% and most preferably 70 wt%, based on the total weight of the elastomeric block copolymers. Blends of improving entrance elastomeric copolymers comprising high levels of isoprene-containing block copolymers show fewer tendencies to form gels in following, extrusion processes versus elastomeric block copolymers containing butadiene blocks. Preferably, the improving polymer blend composition of the r project present invention has a melt flow rate or MFR (grams/10 minutes (g/10 min), 200°C, 5 kg, 2.0955 mm diameter hole; ASTM D-1238, former Condition G) of greater than or equal to 1, more preferably greater than or equal to college entrance, 2, and most preferably greater than or equal to 3, and to write my paper, less than 100, preferably less than 80 and most preferably less than 60. The elastomeric linear block copolymers used in the polymer blend of the present invention preferably contain little or no diblock copolymers. Diblock copolymers are polymers that contain only one monovinylidene aromatic monomer block and one conjugated diene block. The presence of significant amounts of diblock in improving college entrance essays, a linear elastomeric block copolymer results in inferior properties in elastomeric articles prepared from such a block copolymer relative to the same properties of inspiration to write my paper elastomeric articles prepared from compositions of the invention, for entrance essays example, lower stress retention. Preferably, any diblock copolymers are present in thesis abstract before or after, linear block copolymers at an amount of 5 wt%, more preferably 2 wt%, based on the total weight of the elastomeric block copolymer. The presence of diblock copolymers can be prevented by utilizing a sequential polymerization process. Such sequential polymerization processes are well known in the art and preferred for the preparation of the essays block copolymers used in this invention, as disclosed in U.S.
Patents 5,242,984 and 5,134,968, both of which are incorporated herein by reference. Thesis Before Or After Of Contents? If elastomeric radial block copolymers, which are typically produced via a coupling process, are used in the polymer blend compositions of the improving essays present invention, larger amounts of diblock copolymers can be tolerated. Preferably, the diblock copolymers are present in Stakeholders, radial block copolymers at an amount of 15 wt%, more preferably 10 wt%, and college, most preferably 6 wt%, based on the total weight of the radial block copolymer. In addition to the elastomeric block copolymer A and the thermoplastic block copolymer B, the inspiration to write polymer blend of the present invention can also comprise other additives commonly used in improving college entrance essays, polymer compositions such as extenders, slip agents, pigments, anti- oxidants, heat stabilizers, photostabilizers and the like. In a preferred embodiment, the blend of the present invention does not contain any significant amount of Stakeholders additional polymers besides the improving entrance essays elastomeric and thermoplastic copolymers.
A significant amount refers to following statement, amounts which would substantially alter the physical properties of the improving blend and is typically greater than 5 wt%, based on the total weight of A, B and C. Specifically, the polymer blend composition of the present invention optionally contains an extender oil C, which comprises hydrocarbon oils, polymers or oligomers derived from monomers having olefinic unsaturation compatible with the conjugated diene block, or mixtures thereof. Extenders include aliphatic hydrocarbon oils or naphthenic oils, or mixtures thereof, with aliphatic hydrocarbon oils such as white mineral oil being most preferred. The extender or oil, if used, is typically present in an amount of from 1 wt%, preferably from 2 wt%, more preferably from 3 wt% and statistics, most preferably from 4 wt% to 30 wt%, more preferably to 25 wt%, and most preferably to 20 wt%, based on the total weight of A, B, and C. College Entrance Essays? The polymer blend composition of the present invention may further include slip agents, as disclosed in U.S. Patent 4,476,180, which is incorporated herein by runner father/son, reference. Examples of such agents are those commonly derived from amides of fatty acids having from 12 to 22 carbon atoms. Such slip agents are commonly incorporated in compositions in amounts of from 0.05 pbw to 5 pbw of the polymer blend composition. Such slip agents should be used at minimal levels so as not to impart opacity or increases in haze or reduction in transparency to the blend. Heat stabilizers and antioxidants include TRGANOX ® 1010 tetrakis(methylene (3,5- di-tert-butyl-4-hydroxyhydrocinnamate)) methane, TRGANOX ® 1076 octadecyl 3,5-di-tert- butyl-4-hydrohydroxycinnamate and TRGANOX ® 565 4-((4,6-bis(octylthio)-s-triazin-2- yl)amino)-2,6-di-tert-butylphenol. Secondary antioxidants may also be used with primary antioxidants, for example aromatic phosphite compounds such as tris-nonyl-phenol phosphite.
Heat stabilizers and improving essays, antioxidants are incorporated in the compositions of the invention at a level of from r project, 0.05 pbw to 1.5 pbw, based on the total weight of the polymer blend composition. Improving Essays? Such antioxidants should not impart opacity or increases in haze or reduction in transparency to r project statistics, the blend. Examples of preferred photostabilizers include derivatives of improving college benzophenone. Such photostabilizers are generally incorporated in the polymer blend composition at a level from print, 0.1 pbw to 3 pbw of the college polymer blend composition. Such photostabilizers should not impart opacity, increase haze or reduce transparency of the blend. In some applications, pigments may be desired to color the transparent blend or impart a level of opaqueness. Pigments are typically added to the polymer blend composition in the form of concentrates, at levels of from 0.5 pbw to 5 pbw, based on the total weight of the polymer blend composition. R Project Statistics? Polymers used as concentrate carriers should have similar refractive indices to the refractive index of the polymer blend.
Any combination of the optional constituents described herein above maybe used in the polymer blend composition of the present invention. The copolymers utilized in the polymer blend of the present invention can be produced by a traditional anionic polymerization process, using existing aliphatic solvents and process equipment. The copolymers can be blended together in a vessel, optionally with an college extender oil; extruded and abstract table, devolatilized to produce a single pellet product, for conversion into, for example, films, fibers, non-woven products and college entrance essays, injection molded articles. The elastomeric and thermoplastic block copolymers can be made separately, in different reactors or can be prepared simultaneously within the same reactor. In one embodiment, the following statement present invention is related to a process of producing a blend of college entrance a thermoplastic copolymer and an elastomeric copolymer, comprising: -polymerizing a monovinylidene aromatic monomer and a diene monomer to produce an elastomeric block copolymer polymerization mixture comprising a block copolymer of less than 50 wt% monovinylidene aromatic monomer, based on the total weight of the block copolymer; -polymerizing a monovinylidene aromatic monomer and a diene monomer to produce a thermoplastic block copolymer polymerization mixture comprising a block copolymer of at least 50 wt% monovinylidene aromatic monomer, based on the total weight of the block copolymer; -contacting the r project elastomeric copolymer polymerization mixture with the improving thermoplastic copolymer polymerization mixture to form a blended polymerization mixture; -devolatilizing the blended polymerization mixture to form a blended polymer product, and -pelletizing the blended polymer product. In one embodiment, the elastomeric and Stakeholders, thermoplastic block copolymers are produced simultaneously in an anionic reaction process, with the optional addition of an extender oil prior to extrusion into pellets. Additional components such as slip agents, stabilizers, pigments, and improving college essays, the like, can be added to the blending process prior to pelletization or added to the extrusion process via separate feeding system as is typically done in statement, the industry.
Antiblock agents can also be added to the extruded pellets. This produces a finished product that does not require further compounding or mastication prior to extrusion into improving a converted article such as film, fibers, non- woven articles and injection molded articles. If the elastomeric and thermoplastic copolymers are produced separately via anionic polymerization, the final composition of the invention and statement, optional additives, such as the extender oil, can be prepared by contacting the ingredients in an appropriate mixing device such as an extruder, twin-screw extruder or a high efficiency mixer typically used for thermoplastics or thermoplastic elastomers. However, it is college entrance essays preferred to blue, blend the college components prior to extrusion or further processing. Furthermore, if the elastomeric and thermoplastic copolymers are produced separately, the mixing can be performed in the process of blue print forming an article, for improving entrance essays instance, in before table, a blown or cast film process, an injection molding process, or a fiber spinning process with multiple feed systems and college entrance, the appropriate mixing screw and extruder design. The polymer blend composition of the present invention produces articles having the r project following properties and advantages: a tensile strength greater than 10.0 megapascals (MPa); a peak force at 200 percent elongation of greater than 0.7 MPa a set of 15 percent (%) or less; a stress relaxation of 20% or less; a % haze of less than 50%; and a % transparency of entrance essays greater than 75%. As used herein, the essays relationship term tensile strength or tensile stress is college entrance essays defined by the following equation: Tensile stress MPa = F / A where F = observed force at before or after table of contents specified elongation A = cross-sectional area of unstretched specimen. As used herein, the term elongation is improving college entrance essays defined by the following equation: Elongation (%) = 100(L— L 0 )/Lo where L = observed distance between the bench marks on stretched specimen in the kite runner essays father/son relationship, cm Lo = original distance between the bench marks in improving college, cm. As used herein, the terms set or percent set refer to thesis table of contents, the percent deformation of an elastomeric material measured while the material is in a relaxed condition for a specified period of time (that is, 60 seconds for the Test Methods described herein) after the material is released from a specified elongation without allowing the essays material to snap back completely.
The percent set is expressed as [(zero load extension after one cycle-initial sample gauge length of cycle l)/(initial sample gauge length of cycle l)] ? l00. Zero load extension refers to the distance between the jaws at the beginning of the second cycle before the tensile testing equipment registers a load. As used herein, the term high haze refers to a greater than 50 % value for haze and the terms transparency or highly transparent refers to a greater than 75 % value for total transmission. Haze and total transmission (that is, transparency) are measured using the HunterLab Colorquest XE spectrophotometer which uses d/0° (sphere) geometry for Stakeholders transmission measurements. Improving Entrance? While this haze measurements does not conform to following, ASTM method D 1003, Standard Test Method for Haze and improving college entrance essays, Luminous Transmittance of the kite essays Transparent Plastics, due to differences in instrument geometry, values obtained for improving college entrance certified standards are similar. Haze is equal to the percent of diffuse transmittance relative to r project statistics, the total transmittance of the incident light, where diffuse transmittance is measured from the light forward scattered at angles greater than 2.5°.
Haze and total transmission (that is, transparency) was obtained on improving college entrance essays, plaques 0.125 inch (0.318 cm) thick. In one embodiment, the polymer blend composition useful in preparing transparent elastomeric articles, comprises: (A) from 65 to 92 pbw of one or more elastomeric block copolymer(s) corresponding to one of the the kite runner essays father/son formulas: A-B-R(-B-A) n or A-(BA-) X -BA, wherein each A is a polymer block comprising a monovinylidene aromatic monomer and each B is a polymer block comprising a conjugated diene and optionally a monovinylidene aromatic monomer, R is the remnant of a multifunctional coupling agent, n is an integer from 1 to essays, 5, x is a real number from 0 to blue print, 4; at least 50 wt% of the improving college entrance essays block copolymer is a B block comprised of isoprene or butadiene or combinations thereof; the wt% of monovinylidene aromatic monomer in the block copolymer is less than 50 wt% and is most preferably from 8 to following, 35 wt%, based on the total weight of the elastomeric block copolymer; the total block copolymer composition contains no more than 5 wt% of a diblock of the formula B-A; the block copolymer has a MFR of from 0.1 to 50 g/10 min.; and the elastomeric block copolymer comprises styrene and butadiene; styrene and isoprene; styrene, isoprene and butadiene; or any combination thereof; and. (B) from 8 to 35 pbw of one or more thermoplastic block copolymer(s) corresponding to one of the formula: A-B-R(-B-A)n or A-(BA-) X — BA or B y -(AB-) Z -AB: wherein each A is a polymer block comprising a monovinylidene aromatic monomer and each B is a polymer block comprising a conjugated diene and optionally a monovinylidene aromatic monomer, R is the improving remnant of a multifunctional coupling agent, n is an integer from 1 to 5, x is a real number from inspiration my paper, 0 to entrance essays, 4, y is statistics 0 or 1, and z is a real number from 0 to 4; less than 50 wt% of the block copolymer is a B block comprised of isoprene or butadiene, the weight percent of entrance monovinylidene aromatic monomer in the block copolymer is 50 wt% or more, more preferably 65 to Stakeholders, 95 wt%; the block copolymer has a MFR of from 0.1 to 50 g/10 min.; and improving, the thermoplastic block copolymer comprises styrene and butadiene; styrene and isoprene; or styrene, isoprene and butadiene; and. (C) from 0 to 35 pbw of an extender oil, based on the total weight of A, B and C. Stakeholders? Extrusion blown films may be prepared from the polymer blend compositions of the present invention using standard equipment, standard techniques and typical conditions. A die gap of essays 5 to 120 mils (127 micrometers (?m) to 3048 ?m) is acceptable, a gap of 10 to Stakeholders, 80 mils (254 ?m to improving entrance, 2032 ?m) is preferred, and statement, a gap of 20 to 50 mils (508 ?m to 1270 ?m) is most preferred. Melt temperatures of 170°C to 232°C are acceptable and between 175°C and essays, 215°C are preferred. A blow-up ratio of 1 : 1 to 10: 1 is preferred. Rapid cooling of the extruder blown film is preferably performed by a dual lip cooling ring. Due to r project, the low modulus of the film produced from the composition of this invention, a roller-collapsing frame is preferred to avoid bubble chatter. A film which is extrusion blown from the polymer blend composition of the present invention is typically between 0.5 and 10 mils (12.7 ?m to 254 ?m) in improving entrance essays, thickness, and abstract or after, is preferably between 1 and college entrance essays, 6 mils (25.4 ?m to 152.4 ?m) in thickness and is most preferably between 1.5 and 4 mils (25.4 ?m to 101.6 ?m) in thickness. Cast films can be processed at extruder conditions and die gaps similar to extrusion blown films.
Melt temperatures of 170°C to 232°C are acceptable and between 175°C and 215°C are preferred. The Kite Essays? Draw down ratios of 1 : 1 to improving college essays, 2: 1 are preferred for monolayer films. Cast films can be coextruded with the incorporation of statistics one or two skin layers over improving, the elastic core and can be produced at higher draw ratios. Stakeholders? As used herein, the improving essays term skin layer refers to a layer comprising a thermoplastic polymer or polymeric blend. The skin layer can comprise for following statement example polyolefins, such as polyethylene and/or polypropylene, ethylene copolymers such as ethylene vinyl acetate copolymers, polystyrenes, styrene-butadiene copolymers (such as K-RESIN™), styrene-isoprene copolymers, or blends thereof, that are substantially less elastomeric than the elastomeric layer. The skin layer is considered substantially less elastomeric if the permanent set of the skin layer is at improving college least 20 % greater than that of the elastomeric layer. Permanent set refers to the deformation of a material measured in a sufficient time after the r project material is released from a specified elongation to allow the material to snap back fully. The skin layer should be a transparent material to allow the combined films structure to maintain its transparency. Some melt mixing can occur at the film interfaces and create a film that is less transparent. Entrance? Those skilled in the art of coextrusion understand this phenomena.
A preferred skin layer is produced from commercially available film grade styrene-butadiene copolymers offered by thesis, Chevron Phillips know as K-RESIN™. Block copolymers of monovinylidene aromatic and diene monomers can also be used as skin layers, wherein the improving college essays block copolymer comprises from relationship, 35 to 95 wt% monovinylidene aromatic based on the total weight of the block copolymer. Monovinylidene aromatic and improving essays, diene monomers are as described previously in the present specification. (Note: the thermoplastic block copolymers described in the present invention can additionally be used as skin layers in multi-layer films). This invention relates to a composition useful for preparing transparent elastomeric articles such as films, fibers, non- woven articles, and injection molded parts and extruded profiles. Stakeholders? The articles of this invention may be used in a wide variety of applications where transparent elastomeric materials are useful, as well as in elastomeric applications where transparency is not required.
In particular, such articles are useful as low cost elastic members for disposable wearing apparel such as diapers, medical gowns and improving entrance, disposable dresses. In another embodiment, the invention comprises elastomeric articles comprising the composition of the invention to produce monolayer elastomeric films, coextruded elastomeric films (that is, containing one or two thermoplastic skin layers such as a three layer film for example: styrene-butadiene copolymer skin — elastomeric composition — styrene-butadiene copolymer skin), co-extruded fibers and spun bond non-wovens articles produced from said fibers. The composition of the invention prepares elastomeric articles with good elastic properties. For films or compositions produced with a skin layer(s), the film must be tentered or activated prior to use as an elastic article. The addition of the skin layer makes the print elastic article more suitable for conventional film production, in printing operations as well for the production of apertured film. TEST METHODS. A. Tensile Strength And Elongation At Failure. Test specimens are obtained from compression molded samples using an ASTM. D1822 Type L die with 1.28 centimeter (cm) tabs.
Films are cut into 2.54 cm strips in the machine direction (MD) of the film by 15.24 cm long in the transverse direction (TD) (the transverse direction which is at a 90° angle from MD) specimens. Improving College Entrance? The tensile stress-strain properties of the Stakeholders compression molded plaque samples are determined according to ASTM. Method D412-87 and ASTM Method D882-91 for improving college essays the film samples. Stakeholders? The average result of three samples is improving college reported. B. Hardness Test. Shore A durometer hardness is determined according to ASTM D 2240 using a. Model 716A Durometer Hardness System available from Shore Instruments.
Sample plaques of 3.175 millimeter (mm) thickness were stacked to statistics, a thickness of 6.35 mm thickness before testing. C. Melt Flow Rate. Tested in accordance with ASTM D-1238, at conditions 200 degree centigrade (°C)/ 5 kg using a standard die with a 2.0955 mm diameter hole (formerly known as Condition. D. Two Cycle Hysteresis Test Test specimens are obtained from compression molded samples using an ASTM. Dl 822 Type L die with 1.27 cm or from entrance essays, films. Films are cut into 2.54 cm strips in the machine direction (MD) by 10.16 cm long in the transverse direction (TD). The two-cycle hysteresis is measured at room temperature(about 23° C.) with extension to 200 % strain. The hysteresis properties of the following samples are based on ASTM Method D4649-87.
E. Optical Properties. Haze and transparency values were determined with a Hunter Lab Tristimulus. Colorimeter Model D25P-9 with glass test standard numbered 425 in accordance with. ASTM Method D 1003-92 on improving college entrance essays, 3.175 mm thick plaques. F. Molecular Weight of Polymer When measuring molecular weights, the technique employed is that of gel permeation chromatography employing a polystyrene standard. Molecular weights for all blocks or polymers except polystyrene based block or polymers, are corrected according to the method disclosed in Runyon et al., J. of Applied Polymer Science 13, 2359 (1969) and Tung, J. of Applied Polymer Science 24, 953 (1979). The following examples are provided to illustrate the present invention. The examples are not intended to limit the r project scope of the improving entrance present invention and they should not be so interpreted. Abstract? Amounts are in weight parts or weight percentages unless otherwise indicated. Essays? Elastomeric Block Copolymer Preparation.
BCP-1 (Block Copolymer Preparation- 1 is a method for preparing a styrene linear elastomeric styrene-isoprene-styrene (SIS) block copolymer.) To a 18.5 liter stirred reactor under a nitrogen atmosphere is added 13.68 kilograms. (kg) of hydrocarbon solvent which consists of Stakeholders approximately 90% cyclohexane and 10% n-hexane by weight. Essays? For solvent purity, the reactor is blanked by adding 11.5 grams (g) of a cyclohexane solution which is 0.1195 molar in low molecular weight polystyryl lithium. At a temperature of 75.6°C, 93.0 g of or after a 0.220 molar solution of sec-butyllithium in cyclohexane solvent are added followed by 322.9 g of styrene. The polymerization is allowed to continue for 69 minutes, and then 1581 g of isoprene are added at 65°C which polymerizes and improving entrance, reaches a peak temperature of inspiration my paper 94.2°C. At the improving entrance essays end of 14 minutes, the temperature is cooled to 76.9°C, and then 322.9 g of styrene monomer is added and allowed to Stakeholders, polymerize for 17 minutes. To quench the reaction, 3.5 milliliters (ml) of isopropanol is added. Improving Entrance? After removal from the reactor, retained aliquots of solution are neutralized with phosphoric acid at a molar ratio of 0.4 mole acid per mole of lithium agent added per unit volume of Stakeholders liquor. Prior to improving college entrance essays, recovery by devolatilization of volatile compounds in a vacuum oven set at 100°C for a minimum of 3 hours, phenolic antioxidant is added at a level of 1250 parts per million parts (ppm) of base polymer and phosphite antioxidant is added at a level of runner essays father/son 3000 ppm of base polymer. Analysis by essays, size exclusion chromatography shows a single main peak with a number average molecular weight (Mn) of 83,000 on a polystyrene calibration basis and a peak maximum at 108,000 on a polystyrene calibration basis.
This polymer is identified as a elastomeric styrene-isoprene-styrene (SIS) block copolymer, containing 29 wt% styrene. R Project Statistics? Thermoplastic Block Copolymer Preparation. BCP-2 (Block Copolymer Preparation-2 is a method of preparing a styrene linear thermoplastic styrene-isoprene-styrene (SIS) block copolymer.) To a 18.9 liter stirred reactor under a nitrogen atmosphere is improving entrance essays added 13.95 kg of statistics hydrocarbon solvent consisting of approximately 90% cyclohexane and 10% n-hexane by weight. Entrance? For solvent purity, the reactor is blanked by adding 12.9 g of a cyclohexane solution which is 0.1195 molar in low molecular weight polystyryl lithium. At a temperature of 82.1 °C, 73.0 g of a 0.220 molar solution of sec-butyllithium in before, cyclohexane solvent are added followed by 851.6 g of essays styrene.
The polymerization is allowed to continue for 25 minutes, and then 567.7 g of isoprene is added at 72.1°C which polymerizes and reaches a peak temperature of Stakeholders 78.3°C. At the end of 11 minutes, the temperature is college entrance essays cooled to 71.2°C, and then 851.6 g of styrene monomer is added and allowed to polymerize for 20 minutes. Statistics? To quench the entrance essays reaction, 3.5 ml of isopropanol is added. After removal from the reactor, retained aliquots of solution are neutralized with phosphoric acid at a molar ratio of 0.4 mole acid per mole of lithium agent added per blue print, unit volume of liquor. Prior to recovery by devolatilization of volatile compounds in a vacuum oven set at 100°C for a minimum of 3 hours, phenolic antioxidant is added at a level of 1000 ppm of base polymer and essays, phosphite antioxidant is added at following statement a level of 1000 ppm of base polymer. Analysis by size exclusion chromatography shows a single main peak with a Mn of 111,200 on improving college entrance essays, a polystyrene calibration basis and a peak maximum at Service blue 122,200 on a polystyrene calibration basis.
This polymer is identified as a thermoplastic styrene-isoprene-styrene (SIS) block copolymer, containing 75 wt% styrene. Simultaneous Elastomeric and Thermoplastic Block Copolymer Preparation. BCP-3 (Block Copolymer Preparation-3 is a method for preparing a blend of entrance essays elastomeric and table of contents, thermoplastic block copolymers simultaneously.) To a 18.9 liter stirred reactor under a nitrogen atmosphere is improving college entrance essays added 13.71 kg of hydrocarbon solvent consisting of approximately 90% cyclohexane and 10% n-hexane by weight. For solvent purity, the reactor is blanked by adding 10.5 g of a cyclohexane solution which is Stakeholders 0.117 molar in low molecular weight polystyryl lithium. At a temperature of improving college entrance 76°C, 11.0 g of a 0.220 molar solution of sec-butyl lithium in cyclohexane solvent is r project added followed by 272.7 g of styrene. The polymerization is allowed to continue for 41 minutes, and then 44.1 g of a 0.220 molar solution of improving entrance sec-butyl lithium in cyclohexane solvent is added followed by 186.2 g of Stakeholders styrene. The polymerization is allowed to continue for improving essays 105 minutes, and then 1551.8 g of isoprene is added at 83.3°C.
At the end of 16 minutes, the temperature is cooled to 71.4°C, and then 189.3 g of styrene monomer is added and allowed to polymerize for 77 minutes. To quench the reaction, 3.5 ml of isopropanol is added. After removal from the reactor, retained aliquots of solution are neutralized with phosphoric acid at a molar ratio of following 0.4 mole acid per improving college entrance, mole of lithium agent added per unit volume of liquor. Prior to recovery by devolatilization of volatile compounds in a vacuum oven set at r project 100°C for a minimum of 3 hours, phenolic antioxidant is added at a level of improving college entrance essays 1000 ppm of base polymer and phosphite antioxidant is added at a level of 1000 ppm of Stakeholders base polymer. Analysis by entrance essays, size exclusion chromatography shows two peaks, one with a Mn of to write my paper 135,555 on a polystyrene calibration basis and another peak with a Mn of 189,080 on essays, a polystyrene calibration basis. This polymer is identified as a blend of elastomeric styrene-isoprene-styrene (SIS) and thermoplastic styrene-isoprene-styrene (SIS) block copolymer, containing an average of 31.0 weight percent styrene. The peak with the Mn of 135,555 has a styrene content of 19.4 wt% and father/son relationship, the peak with the Mn of 189,080 has a styrene content of improving essays 53.1 wt%. EXAMPLES EXAMPLES 1-5. Comparative Example 1 utilizes a high molecular weight thermoplastic homopolymer polystyrene (PS-1) product blended with a linear elastomeric styrene- isoprene-styrene (SIS-1) block copolymer. Comparative Example 2 contains a high molecular weight thermoplastic homopolymer polystyrene (PS-1) product blended with a linear elastomeric styrene- isoprene-styrene (SIS-1) block copolymer and mineral oil.
Comparative Example 3 is a blend of a 29 wt% styrene containing elastomeric styrene-isoprene-styrene (SIS-1) block copolymer and mineral oil. Example 4 contains a 75 wt% styrene containing linear thermoplastic styrene- butadiene-styrene-butadiene (PS-2) block copolymer blended with a 29 wt% styrene containing elastomeric styrene-isoprene-styrene (SIS-1) block copolymer and following statement, mineral oil. Example 5 contains a 75 wt% styrene containing linear thermoplastic styrene- butadiene-styrene-butadiene-styrene (SBSBS) pentablock copolymer (PS-3) blended with a 29 wt% styrene containing elastomeric styrene-isoprene-styrene (SIS-1) block copolymer and mineral oil. Process Comparative Example 1 20 g of PS-1 and 80 g of improving college entrance SIS-1 are added to Service blue print, a 0.9472 liter jar and college entrance essays, filled with 0.5 liter of cyclohexane. The polymer solution is placed on a shaker for 24 hours to allow the polymer to go into solution. To Write My Paper? The resultant solution is then placed in a devolatilizing oven and entrance essays, the solvent is removed. The resulting polymer blend is then collected and to write, 45 g placed on a pre-heated Farrel 3 x 7 (7.6 cm x 17.8 cm) roll mill (Model 3FF500) at improving college essays 155°C roll temperature for 90 seconds.
The sheet is inspiration to write removed and used for subsequent testing. Sheets are prepared (approximately 0.94 mm thick) using a pre-heated molding press (PHI Model SB234C-X-MS-X24) at 200°C platen temperature. 7.0 to 7.5 g of the above roll mill specimen is entrance essays evenly distributed into a 75 mm wide by 115 mm high by 0.94 mm thick chase layered between TFE-coated glass sheet and metal backing plates. The specimen is molded as follows: pre-heat 3.0 minutes at minimal pressure; medium force 0.5 minutes (10,000 kg ram force); material cure 3.0 minutes (20,000 kg ram force); cooling period 4.5 minutes (20,000 kg ram force, ambient temperature water cooling). The specimens are stored at least 24 hours at r project statistics 23 °C and then die-cut using an college ASTM-D 1822 Die L for Stakeholders tensile and improving college, hysteresis testing. Service? Initial gauge length is 25.4 mm and 3 specimens per improving entrance essays, compound are tested.
Tensile samples are pulled in statement, the roll mill direction and college entrance, hysteresis samples are pulled transverse to the roll mill direction. The properties are shown in Table 1. Comparative Example 2-The process of Comparative Example 1 is repeated using 15 g of. PS-1, 80 g of blue SIS-1 and 5 g of mineral oil. Comparative Example 3 -The process of Comparative Example 1 is repeated using 88.2g of. SIS-1 and 11.8 g of mineral oil. Example 4-The process of Comparative Example 1 is repeated using 15 g of PS-2, 75 g of.
SIS-1 and 10 g of mineral oil. Example 5 -The process of Comparative Example 1 is repeated using 15 g of PS-3 -, 75 g of. SIS-1 and college entrance, 10 g of mineral oil. -PS-1 is a free radically produced general purpose, thermoplastic homopolymer polystyrene (The Dow Chemical Company STYRON™ 68 5 ), with peak Mw 323,800 and MFR of 1.7 g/ 10 rninute (200 ° C). -PS-2 is a 75 wt% styrene, thermoplastic styrene-butadiene-styrene (SBS) block copolymer, with peak Mw 103,000 and MFR of to write my paper 8.1 g/ 10 minute (200 C C). -PS-3 is college a 75 wt.% styrene, thermoplastic styrene-butadiene-styrene-butadiene-styrene (SBSBS) block copolymer, with peak Mw 95,000 and inspiration, MFR of 7.2 g/ 10 minute (200 ° C). -SIS-1 is a 29 wt% styrene containing, elastomeric styrene-isoprene-styrene (SIS) triblock copolymer known as VECTOR™ 4211 , available from Dexco Polymers LP, with peak Mw 96,000 and MFR of 12.0 g/ 10 minute (200 ° C). -The mineral oil (MO) used is a white mineral oil with 200 centipoise (CPS) viscosity known as Witco 200, available from college entrance essays, Witco Chemical Co. For Comparative Examples 1 and 2, containing polystyrene homopolymers, the Service blue print compositions show good tensile strength, peak force, stress relaxation and set.
However, they show very high haze and a relatively low level of transparency. A virtually opaque elastomeric product is produced. Comparative Example 3 containing the styrene-isoprene-styrene copolymer and mineral oil, shows significantly better optical properties. A highly transparent elastomeric product with low haze is improving college entrance produced. Thesis Abstract Table Of Contents? However, experience tells us that this medium (18 to 33 wt%) styrene elastomeric block copolymer with oil cannot be easily extruded into improving entrance essays an elastomeric article. Abstract Or After Of Contents? Successful extrusion requires an essays elastomeric block copolymer containing more than 33 wt% styrene and more preferably 40 wt% styrene or additions of at least 5 wt%, more preferably 10 wt% and following, most preferably 15 wt% of a thermoplastic polymer or thermoplastic block copolymer.
Therefore, although it has good overall properties, and specifically low haze and improving entrance, high transparency, it has little commercial value. Example 4 contains PS-2, SIS-1 and mineral oil. This product shows similar physical, and elastic properties to Comparative Example 2, however, a transparent elastomeric product is produced. Example 5 contains PS-3, SIS-1 and runner father/son, mineral oil. This product shows similar physical, elastic and improving, transparency properties to Example 4.
Example 6-A commercially available thermoplastic styrene-butadiene block copolymer (SBS) product (PS-4 ) is blended with an elastomeric styrene-isoprene-styrene (SIS) block copolymer. The blend contains low levels of slip agent to aid its cast extrusion into a film. It contains no mineral oil. 2830 g of PS-4, 8500 g of SIS-1, and 28.4 g of slip agent (KEMAMIDE™ E Ultra from statement, Crompton Plastics Additives) is blended in a 500-liter ribbon blender for 30 minutes, then compounded and pelletized on improving entrance essays, a Werner Pfliederer ZSK-70 twin-screw extruder equipped with a Gala pelletizer (1 atmospheric vent, 24 die holes of 6.35 mm diameter). The extruder is operated at 200 to 300 rpm, 145 to 215°C. Film is cast from pellets using a cast extruder set-up attached to a Davis Standard single-screw extruder with a 48 mm diameter die. Statement? Temperatures are 160-225° centigrade. Improving College Entrance? The film thickness is 0.013 inch (in) or 0.33 mm and is tested in the transverse or cross direction. The properties are shown in the Table 2. -PS-4 is an anionicalfy produced radial styrene-butadiene copolymer known commercially as K-Resin™ DK-13. The MFR is 10.0 g 10 minute (200 °C). It is prepared according to patents referenced by Chevron Phillips Chemical Co. -SIS-1 is to write my paper as stated previously.
Example 6 shows that a blend of a thermoplastic styrene-butadiene block copolymer and an elastomeric block copolymer, with no mineral oil, can make a commercially viable transparent elastomeric film product. Example 7-The process of Comparative Example 1 is repeated with 20g of PS-5, 75g of SIS-2 and entrance essays, 5g of mineral oil. Example 8-The process of Comparative Example 1 is repeated with 15g of PS-6 and abstract before or after table, 85g of college entrance SIS-2. Example 9-The process of thesis before or after table of contents Comparative Example 1 is repeated with 15g of PS-7, 70g of SIS-2 and 15g of mineral oil. Example 10-The process of Comparative Example 1 is repeated with 20g of PS-8, 70g of SIS-2 and lOg of college mineral oil. Example 11 -The process of abstract table Comparative Example 1 is repeated with 15 g of PS-9, 75g of SIS-3 and lOg of mineral oil. -PS-5 is improving college essays a 75.5 wt% styrene, thermoplastic styrene-isoprene-styrene (SIS) block copolymer.
The peak Mw is following 112,000 and the MFR is. 6.5 g/ 10 minute (200 °C). -PS-6 is a 81.4 wt% styrene, thermoplastic styrene-isoprene-styrene (SIS) block copolymer. The peak Mw is 108,000 and the MFR is. 15.7 g/ 10 minute (200 °C). -PS-7 is a 86.5 wt% styrene, thermoplastic styrene-isoprene-styrene (SIS) block copolymer. The peak Mw is 109,000 and the MFR is. 20.0 g/ 10 minute (200 °C).
-PS-8 is a 75.5 wt% styrene, thermoplastic styrene-isoprene-styrene (SIS) block copolymer. The peak Mw is 130,000 and college, the MFR is. 36 g/ 10 minute (200 °C). -PS-9 is a 71.5 wt% styrene, thermoplastic styrene-isoprene-styrene (SIS) block copolymer. The peak Mw is 131,000 and the MFR is. 33 g/ 10 minute (200 °C). -SIS-2 is a 30 wt% styrene containing, elastomeric styrene-isoprene-styrene (SIS) triblock copolymer. The Kite Essays? The peak Mw is 104,000 and improving college essays, the. MFR is to write my paper 6.2 g/ 10 minute (200 °C) -SIS-3 is a 30.2 wt% styrene containing, elastomeric styrene-isoprene-styrene (SIS) triblock copolymer. Essays? The peak Mw is 95,000 and the.
MFR is 14.0 g 10 minute (200 °C). Example 12- A linear, elastomeric styrene-isoprene-styrene (SIS-3) block is solution blended with a thermoplastic styrene-isoprene-styrene (SIS) block copolymer (PS-9) in a mix tank with mineral oil in blue, a ratio of entrance essays SIS-3/PS-9/MO of 75 : 15 : 10. The solution is fed to statement, a devolatilizing extruder and approximately 275 Kg of pellets are produced. Film is cast from improving college, pellets using a cast extruder set-up attached to a Davis Standard single-screw extruder (48 mm diameter die, 160 -225° C). The film thickness is 0.0036 in. (0.091 mm). Properties are shown in Table 4. Example 12 shows that a blend of a thermoplastic styrene-isoprene block copolymer and an elastomeric block copolymer, with mineral oil, can be produced on the semi- commercial scale to make a commercially viable transparent elastomeric film product. Surprisingly, the combination of an following elastomeric block copolymer with a thermoplastic block copolymer produces a transparent elastomeric article having low haze and high transparency. Example 13 -The process of Comparative Example 1 is repeated with 20 g of PS-8, 42 g of SIS-2, 28 g of SBS-1 and 10 g of mineral oil. The properties are shown in Table 5. -SBS-1 is a 31 wt% styrene containing, styrene-butadiene-styrene (SBS) triblock copolymer known as VECTOR™ 2518, available from Dexco Polymers LP). The peak Mw is 102,000 and the MFR is 6.0 g/10 minute (Modified MFR Conditions 200°C/10 Kg, 0.1564 in. capillary)
Example 13 shows that a blend of improving college a thermoplastic styrene-isoprene-styrene block copolymer and two different elastomeric block copolymers, a styrene-isoprene-styrene block copolymer and a styrene-butadiene-styrene block copolymer, with mineral oil, can produce an elastomeric film product. Surprisingly, the r project statistics combination of two elastomeric block copolymers with a thermoplastic block copolymer produces a transparent elastomeric article having low haze and high transparency. Process for Preparation of college entrance Polymer Example 14. The high styrene content block copolymer component and the low styrene content block copolymer components are produced simultaneously in a single reactor. Runner Essays Father/son? Thus, 45g of the polymer is placed on a pre-heated Farrel 3 in. x 7 in. Essays? (7.6 cm x 17.8 cm) roll mill. (Model 3FF500) at 155°C roll temperature for inspiration my paper 90 sec.
The sheet is entrance essays removed and used for subsequent testing. Sheets are prepared (approx. 0.94 mm thick) using a pre-heated molding press (PHI Model SB234C-X-MS-X24) at 200°C platen temperature. 7.0 g to 7.5 g of the roll mill specimen is evenly distributed into a 75 mm wide by 115 mm high by 0.94 mm thick chase layered between tetrafluoroethylene (TFE)-coated glass sheet and metal backing plates. The specimen is statement molded as follows: pre-heat 3.0 min. at improving minimal pressure; medium force 0.5 min. Thesis Abstract Or After? (10,000 kg ram force); material cure 3.0 min. (20,000 kg ram force); cooling period 4.5 min. (20,000 kg ram force, ambient temp, water cooling). The specimens are stored at college entrance essays least 24 hours at 23 °C and then die-cut using an ASTM-D 1822 Die L for the kite essays relationship tensile and hysteresis testing. Initial gauge length is 25.4 mm and 3 specimens per compound are tested. Tensile samples are pulled in improving, the roll mill direction and hysteresis samples are pulled transverse to father/son relationship, the roll mill direction. Example 14-The product produced according to BCP-3 is a bimodal distribution product containing a high molecular weight, high styrene content, SIS block copolymer and a medium molecular weight, low styrene content, SIS block copolymer product (SIS-4). The properties are shown in improving college entrance, Table 6. Example 15 -The process of Example 1 is repeated with 90g of abstract before table of contents SIS-4 and lOg of mineral oil.
The properties are shown in Table 6. SIS-4 contains two styrene-isoprene-styrene (SIS) copolymers produced simultaneously in the same reactor vessel. Improving Entrance? The peak Mw for abstract or after one of the polymers is 101,824 and the other is 158,873. The styrene content is 31.0 wt. % and MFR is 13.2 g/ 10 min. Example 14 shows that a product produced via dual initiation can yield a commercially viable transparent elastomeric polymer having low haze and high transparency.
Example 15 shows that the addition of mineral oil produces a softer, more processable, transparent elastomeric polymer versus Example 14.
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Essay On Celebrity Gossip Essays and Research Papers. ? Celebrity Gossip Industry “Khloe Kardashian Caught With Another Man!” “Kanye Cheats on Kim!” “Was Rihanna Pregnant?” These . are all headlines from celebrity gossip magazines. Entrance Essays? The gossip industry has become a very influence part of our society. Tabloids try to influence us by telling us what to do, what to wear, how to eat, what’s sexy and what’s not. Runner Father/son Relationship? Tabloids discover ways to do more than just commercialize products, they advertise people. Celebrities have become a business in themselves by endorsing. Celebrity , Celebrity magazines , Gossip columnist 1562 Words | 4 Pages. Celebrities should not be idolized. Today I am going to discuss why teenagers and children spend too much time following the lives of . celebrities , and why it creates such a negative impact on improving entrance, young lives in this generation.
Nowadays, celebrities include a wide range of thesis or after, genres. Pop stars like Lady Gaga, actors like Leonardo DiCaprio, comedians like Robin Williams and sport athletes like Ian Thorpe. Improving Entrance? The list of different celebrities goes on, which caters for everyone’s interests. And this is the. Actor , Celebrity , Famous for being famous 989 Words | 3 Pages.
Subject: Media Question is: To what extent is the the kite runner father/son relationship, media impacted by the rise of celebrities ? Media is a huge area which connects people . College? around the world, informs them, entertains and educates them. It is print impossible to imagine a contemporary world without media. Media is the Internet, music, television, advertising and billboards on the streets. One of the most important parts of the improving college entrance, media are celebrities . People originally like to know about the life of famous people, they follow their life. Advertising , Celebrity , Internet 1139 Words | 4 Pages. Celebrity Role Models A state in which the mind is elevated above the reach of ordinary impressions, unconscious of print, sensible objects, and improving essays, . under the influence of Service blue, overpowering emotions celebrities find irresistible and entrance, enticing. Celebrities distinguish themselves in such ways that others admire and want to emulate.
Celebrities are worthy of imitation; everyone needs a role model. The immense amount of following, drug usage that celebrities , athletes, professionals, and politicians take part in has improved. 2009 NBA Playoffs , Bill Clinton , Celebrity 1089 Words | 3 Pages. The celebrity will always be accepted in a judgmental world even if they are brought down at times because their super fans portray them as . idols. Bridge: Celebrities are irresistible to improving college the extent where people always want to be connected with them. The obsession with celebrities has developed rapidly leading them to have a significant impact on statement, many individuals.
They are perceived as being of high social status, which is intriguing to a materialistic world. Thesis Statement: Celebrity is especially. Celebrity , People , Significant figures 1335 Words | 4 Pages. This research essay focuses on the topic of the entrance essays, celebrity phenomenon. Stakeholders? Celebrities impact everyone’s lives, whether . College Entrance Essays? through influence, role model or just because their faces are seen on blue, television, magazines, billboards and so on. Improving College? There are a few things in inspiration, life that occur through sheer coincidence, particularly on college essays, such a massive scale. The issue however, is whether or not the celebrity phenomenon has any value to Service blue society. I take the view, and use supporting evidence, that the celebrity phenomenon is. Bobby Brown , Celebrity , Celebrity Worship Syndrome 1581 Words | 5 Pages. History of Reality TV Celebrities. the early 1970’s with shows like An American Family and Candid Camera.
From then, different authors have discussed the improving, evolution of the genre and how its . personalities were launched into the world of celebrities . The Kite Relationship? In this essay I will summarize the history of reality television and its celebrities and how the audience views the improving entrance essays, uprising of the genre. From the Service, beginning, these shows have provided the entertainment without the actors, making it all seem more real and entrance, defining the genre as “Reality. American Idol , An American Family , Cancellation 1281 Words | 4 Pages. Pressures of Society on essays father/son relationship, Celebrities. Synthesis Essay : Pressures of college essays, Society My topic focuses on essays father/son, societal pressures on celebrities and college, people. While research may . confirm that both celebrities and people have the statistics, same problems, you can’t help but notice that celebrities are more judged. Improving? This is a highly controversial topic because we are so quick to judge someone based on their actions without really knowing them. While some people think celebrities are a bad influence some still think they can also have some benefits to abstract table of contents the community. Actor , Celebrities , Celebrity 1005 Words | 3 Pages. Limosnero(1) Archer Research paper 910214427 Celebrity Obsession Today’s generation has been raised in improving entrance, a . celebrity -obsessed media and, as a result, has consequently made teens idolize these average people that the media deems as “stars”. Inspiration My Paper? It is not just a couple of blurbs here and college entrance, there about celebrities , but instead there are entire shows solely devoted to celebrity gossip . Abstract Or After? People follow the personal lives of college entrance essays, celebrities as if it were their own.
For example, when my sister was in. Adolescence , Celebrity , Celebrity Worship Syndrome 1144 Words | 4 Pages. . IS OUR NEW RELIGION FAME, AND CELEBRITIES OUR ‘GODS’? Are Hollywood news or gossip shows like Entertainment Tonight , Extra , The Insider , and Access Hollywood among the TV programs you regularly watch? Have you ever felt almost giddy with anticipation while standing in father/son relationship, line for tickets to the newest.
Celebrities , Celebrity , Celebrity Worship Syndrome 1757 Words | 6 Pages. is it that when the word ‘ gossip ’ is used, it is done so mostly in a negative connotation? Why is college entrance it that every major world religion cautions . against gossiping? Is it really that bad? The correct answer is ‘no’. It is ignorant to blue discredit gossip as an unnecessary social evil.
Gossip has numerous benefits – at an individual as well as a social level. Let us start with the absolute basic. Why do people gossip ? They gossip because gossiping is enjoyable. Many people gossip just for fun or to blow. Eleanor Roosevelt , Gossip , Morality 488 Words | 2 Pages. Monterroso Professor S ICC1 3 May 2013 The Dilemma of a Celebrity In a time where fabricated stories are indulged like soft drinks, and . tall tales are published for a quick buck, the celebrities of today face unimaginable amounts of improving college, pressure from the constant gaze of the following, public fueled by the watchful eye of the improving college entrance essays, media. Following? Their actions are criticized and essays, constantly made available to the public. Although many people feel that celebrities have a responsibility to be role models, it is not a title. Actor , Celebrity , Vogue 1242 Words | 3 Pages.
products that they want, tag photos in following statement, Facebook, post photos with digital filter through Instagram, post videos when a product can be used as well as how to . use it and others. Above all that, the college, other way to Stakeholders do social media marketing is through celebrity endorsement in a competition to get more customers and improving entrance essays, escalate their brand image as an print, additional value. 2. Research Purpose Social media marketing is improving college essays a type of the kite runner, Internet marketing which seeks to accomplish goals with the contribution of. Celebrity , Electronic commerce , Online shopping 1490 Words | 6 Pages. Celebrity News 1 Introduction Brad and Jennifer, Martha Stewart, and college entrance, Michael Jackson are more than just names of celebrities . we all know so well. Upon mentioning these names the general public would automatically associate their names with the Stakeholders, stories of their being plastered throughout the media from talk shows, magazines, and college entrance, even clothing. The media has become such a dominant part of today’s society, but how much of American culture and ideals are centered on the lives of celebrities portrayed. Celebrities , Celebrity , Celebrity Worship Syndrome 2320 Words | 7 Pages. ?Introduction Each celebrity is an individual human that has achieved public recognition for a reason; this can be due to Stakeholders their creative . College Entrance? talent or based on sporting event (Iqani, 2012: 84).
Despite their achievement, another factor that succeed in captivating the public’s attention is through their body shape. Often, people amazed by celebrity’s body from magazine cover when in thesis or after, fact it is college essays all about image manipulation. Celebrities are human too, not all of them have a perfect shape. Through magazine. Actor , Body shape , Celebrity 1293 Words | 4 Pages. would be like without celebrities ? Celebrities are a big factor that help shape today’s world. We turn on the television, read . R Project Statistics? articles on the internet, books, and even magazines which inform us what a celebrity was wearing when they walked the red carpet. The simple fact is that celebrities are highly profiled in improving entrance essays, the media. We follow their everyday life, struggles, and moments of Service, sadness they may encounter. Improving Essays? Let’s face it, the following statement, information we discover about these celebrities causes us to take into.
Adolescence , Celebrity , Form of the Good 1425 Words | 4 Pages. Scope People in the public eye consists of politicians, athletes, celebrities and college essays, other individuals who are famous. For our presentation . we will be concentrating on statement, celebrities and whether they should expect their privacy to be respected by the media. Media comes in various forms, with the more common ones being newspapers, tabloids, radio, paparazzi, internet, social media and many more. A conflict of improving entrance essays, rights? Article 8 of the European Convention on Human Rights stated that every person.
Privacy , Privacy law 1620 Words | 4 Pages. Celebrities Provide Poor Role Models for Children. Celebrities provide poor role models for thesis or after table children. Improving College? The purpose of this essay is to discuss celebrity role models . and their influence positively or negatively on children. Throughout the world celebrities are role models to many people. Nauta and Kokaly (1999) define role models as “other person’s who, either by exerting some influence or simply by being admirable in one or more ways, have an impact on another”. In these modern times of excessive media coverage and thesis abstract before, the easy access of the improving entrance essays, World. Actor , Angelina Jolie , Brad Pitt 1044 Words | 3 Pages. Dumbed Down by Celebrity Infatuation. put in the back burner behind the Stakeholders, latest celebrity scandal, wardrobe malfunction, and YouTube hit.
Real issues such as the war and its . progress are not headlines but only on shorter time slots. It seems like the importance of entrance, important issues has even been ignored by respectable news organizations and publications. The draw to scandal has even become main news whether its focus is on celebrities or respectable public figures. Runner Essays Father/son? Nobody is safe from gossip and the popularity it has gained is college essays so intense. Angelina Jolie , Brad Pitt , Celebrity 2213 Words | 6 Pages. Gossip in the work place Charlie Brown Peanuts University Prof. Runner Father/son? Writing in college entrance essays, the Disciplines Business Communications EN306B Judy Brown July . 18, 2010 Abstract In every work place environment gossip is very common and almost every working individual has been involved in r project statistics, it in some form or another.
Although gossip is often derogatory most working individuals have either engaged in it or have been a victim of it. Improving? I t can also be referred to following as a form of improving entrance, work place bullying and inspiration to write, have a detrimental. Beth Ditto , Employment , Gossip 1480 Words | 5 Pages. Persuasive Essay : Many people would be happy and satisfied if they were in a relationship with money and fame. Doesn't that seem like the . College Entrance? perfect life?
Everyone begins to think that in life that's all that matters, and runner, that's all they need, nothing could be better. Society dictates our morals, feelings, the way we do things and try's to tell us certain things we do are wrong and college entrance, we need to do them the way they feel necessary. Our generations to come will have no clue what the meaning of a true. Celebrity , Civil disobedience , Concord, Massachusetts 2066 Words | 5 Pages. ‘In the world of celebrity , it is the body that is central to inspiration to write the individual’s success’ Critically explore this statement, using examples to . illustrate your response. Celebrity culture in the twenty first century gives the public a level of excitement and interest that seems, for improving college entrance essays one reason or another, disproportionate.
Nowadays, culture privileges the momentary, the visual and the sensational over enduring, the written, and the rational. Celebrities are described by some as extraordinary individuals. Body mass index , Body shape , Britney Spears 1846 Words | 5 Pages. Cheuk Wong Celebrities are smart? Nah…. Oh, look, Lindsay Lohan is being accused of stealing from a necklace from Service blue print a jewelry store. Yes, what . Improving Entrance Essays? you are reading is runner essays father/son correct.
A necklace. You would think a celebrity with more money than the ninety-nine percent of the population of America would be able to afford an eye-catching necklace. The jewelry store reported the necklace. Entrance? Lohan was eventually caught after being photographed by the paparazzi wearing the necklace and video surveillance confirmed. Celebrity , Herbie: Fully Loaded , Kim Kardashian 2011 Words | 5 Pages. Celebrities are made of Stakeholders, different types of improving, people who all want to live the rich and famous lifestyle. Some celebrities do . everything they can just to statistics be in the public eye but others just accept the improving college entrance essays, fame because they enjoy it. Personally, I feel some celebrities must be mad to do certain things just because they want attention from the media, but I also think other celebrities are happy to enjoy themselves while living the dream. Nowadays, a large number of the lesser known celebrities only become. Actor , Celebrity , Movie star 632 Words | 2 Pages. Is Celebrity Worship Syndrome A Bad Thing?
I have a friend who is an affectionate fan of Super Junior, the famous South Korean boys group. . She can confidently list out the birthdates, height, weight and other details/information of all the thirteen members in the group. Following Statement? She is proud as a Super Junior’s devotee. However, she contemplated and replied me with an awkward smile when I asked her about her parents’ birthdates. Entrance? As ironic as it seems, but this may happen on you too! You could possibly name. Celebrities , Celebrity , Celebrity Worship Syndrome 1848 Words | 6 Pages. Ethical Responsibilities of Celebrities.
Do celebrities have ethical responsibilities to set good examples to young people? Aainaa Azmi Abigail Palmer Raveena Devi Soon Tsuey Jing . To Write? Sanjeetha Raja Segi University College American Degree Program Summer 2012 Do celebrities have ethical responsibilities to set good examples for young people? Young people nowadays need role models more than they ever needed before. We can see that crimes rates involving youngsters are increasing worldwide. Improving College Entrance? One of the following, possible causes is improving college entrance that.
Celebrity , Human , Mary-Kate and Ashley Olsen 2039 Words | 6 Pages. The Toxic Society: Celebrity Culture. ?Yung-Ching, Yang Writing 140 Sec 64715 Amanda Weldy Boyd Assignment #5 2013/04/25 The Toxic Society: Celebrity Culture “Gangnam Style,” . popular K-Pop single released by Psy, musician, received unexpected feedback from the whole world which brought up a novel trend of outrageous dancing gesture and distinguished music style that people were crazy about. Pop singers can be so influential to society boundlessly nowadays that they create a whole new fashion trend or culture for to write people to follow. Celebrities , Celebrity , Celebrity Worship Syndrome 1171 Words | 6 Pages. Thesis Statement: Parents and celebrities influence the child in many ways. Entrance? Parents instill the basic principles of the kite essays father/son, life like personal . hygiene, behavior in public, approach to studies, and college essays, respect for statement others while celebrities influence the major aspects of a person’s character such as the improving college entrance essays, way he/she gets dressed, role in society, career, and personality development.
Personality Development: Parents: Play major role as they are the r project, first influence to the child and should try to develop his personality. Celebrity , Father , Morality 1135 Words | 4 Pages. ? Gossip Sites A recent trend on entrance essays, college campuses today is the thesis abstract before or after, use of college essays, campus gossip sites, where students can post campus . related news, rumors, and basic gossip . These sites were originally set up to promote free speech and to allow participants to Service publish comments anonymously without repercussions from school administrators, professors, and other officials. However, they are now being used to post vicious comments about others. For this project, form an opinion and improving college entrance essays, write a narrative about the. Citation , Website 815 Words | 4 Pages.
Reality vs. Gossip Using news channels or juicy gossip for an update about some celebrity is overly used by relationship the . media, frequently. New reporters take advantage if their careers and rudely butt into other people’s lives based on their social status because reporters need a reason to keep the viewers of their broadcast interested in their channel feed. Improving College? It needs to be more about important things like the father/son relationship, weather or if something catastrophic has or is happening. That is college essays what E! News, a channel dedicated.
Facebook , Internet , Mass media 1199 Words | 3 Pages. How Does the Media Negatively Affect the Public and Celebrities. public and statement, celebrities ? The short answer is yes, it does. Improving College? There are a variety of following statement, reasons for this, but I have leant that the main reason is . money. People within the media industry want to improving college entrance essays get rich, and they want to get rich fast. A prime example of this is the paparazzi. Our obsession with celebrities is to write my paper growing by the day, but have you ever wondered who the paparazzi are? How celebrity’s personal moments get immortalized in gossip magazines? The desire to feed the improving essays, hunger for celebrity news is driving. 21st century , Angelina Jolie , Brad Pitt 999 Words | 3 Pages. Celebrity Essay: Why they deserve the money they make.
famous actors and celebrities receive multi-million dollar salaries. Many people believe these salaries are excessive; others believe they are . justifiable. I strongly feel that they earned their multi-million dollar salaries. Most of us, the common people seem relent the hardships and suffering the familys of the famous go through. Also they endure increasingly long workdays that most of us would not be able to endure, hence that not everyone is Stakeholders a celeb. In addition, celebrities give back millions. Brad Pitt , Celebrity , Oprah Winfrey 1245 Words | 3 Pages. public as well. This essay will discuss the various aspects of celebrity endorsement as a prevailing advertising technique along . with critical evaluation of the entrance, phenomenon of r project, multiple celebrity endorsement as a marketing tool and the and will conclude with taking on overview of possible impacts of this technique on today's marketing world. It is a well known fact that many companies spend huge amount of essays, money to statistics get their products endorsed by prominent public figures ( celebrities ).But why do companies. Advertising , Brand , Celebrities 2330 Words | 7 Pages.
Celebrity Role Models Children Emulate. Celebrity Role Models Children Emulate Gary Gardner July 11, 2010 Com 150 Phyllis Rosenburg Celebrities are all around us . influencing our children; they are on entrance essays, the radio, televisions, computers, ipods and even on cellular phones. Our children hear and see what they do in our homes, cars, stores, and even in their classrooms. Though some celebrities can be a negative influence on children, some can have a positive impact because children will mimic what they see. The Kite Essays Father/son Relationship? There are several celebrities. Actor , Amy Winehouse , Annika Sorenstam 941 Words | 3 Pages. Influence From Celebrities From the improving entrance essays, day we were born, or even earlier when we were created in the uterus, we have been constantly . influenced by our surroundings, whether they are living things or nonliving objects.
Parental genes and nutrition influence the development of Stakeholders, human body. Schools, teachers, peers, and TV shows help form our perspectives of the world which we live in. Among so many sources of entrance essays, influence, the influence of parents and the influence of celebrities are two of thesis abstract before or after table, the. Free will , Imitation , Life 1007 Words | 4 Pages. Celebrity Endorsement-Really A Success Factor for Marketers Sheetal Singla*, Bhai Gurdas Instiutute of Engineering amp; Technology, Sangrur . Improving College Essays? __________________________________________________________________ Abstract: It is a frequently used approach in Stakeholders, marketing for improving all brands. In India, celebrities are idolized as Gods and marketers have been trying their best to tap on this emotional connect with the Stakeholders, celebrities . Today, most of the popular brands are being endorsed by a famous personality. Advertising , Amitabh Bachchan , Brand 1865 Words | 6 Pages. The Stalking of Celebrities Stalking remains Hollywood's recurrent celebrity nightmare.1 Never before have we been able to . Entrance Essays? know as much about a star as we do about Stakeholders a close pal. Thanks to publications and TV shows that cater to improving college the public appetite for celebrity news, there's little privacy for stars. We learn the minor details of their lives--from an early schooling, to first kiss, last divorce, drug problems, hopes and to write my paper, fears.2 Celebrities on their own property are not safe from high-powered lenses.
Abuse , Celebrity , Harassment 1224 Words | 3 Pages. exclusively formulated to suit ethnic skin tones, free from blueish and pasty undertones and also been made suitable for humid and college entrance, hot weather. Wheras . psychographically, they are catering the demanding needs of women today especially the artists and celebrities who tend to inspiration have tight schedule. 2. Promotion objectives As the products are already introduced to college essays the market for years, the Stakeholders, purposes of advertising then could be to remind and persuade customers to opt for their product when considering. Advertising , Brand , Human skin color 940 Words | 4 Pages. Celebrities should not have a right to a private life. The social media nowadays are booming with countless news on celebrities . Improving College? Countless celebrity gossips of who is . currently dating who, what they did when they had gotten drunk, which celebrity was arrested and inspiration, even which starlet has ruined whose relationship (Ortiz n.d.). Improving Essays? The gossips on celebrities from media are endless.
So who are these celebrities and the kite runner father/son relationship, why are they making headlines so much and invading our new feeds? Well, celebrities are also known as public figures and they are idolized by the. Celebrity , Mass media , Michael Jackson 1526 Words | 4 Pages. Submitted by: Anusha Arun M.Des 2nd sem Celebrity Endorser Influence on Attitude towards Advertisements and Brands Abstract The . research paper was written by improving entrance essays Bahram Ranjbarian Associate Professor of inspiration to write, Management, Zahra Shekarchizade, Zahra Momeni, Master Students of Business Management from college entrance The University of Isfahan, Iran. The research was conducted in Iranin 2009 and was published in European Journal of Science in 2010. Following Statement? This study aims to analyze the celebrity endorser influence on attitude toward.
Advertising , Aligarh Muslim University , Arithmetic mean 731 Words | 3 Pages. Celebrity Culture Another trait which defines America’s culture and identity is the culture of celebrities . With plenty of college, . wealth, fame, and attention, celebrities display to Service the middle and lower class citizens the improving entrance, ways of life of upper class citizens and nationwide divas. Moreover, they advance these images of themselves by thesis abstract before table of contents exhibiting their multi-bedroom houses and mansions, multiple vehicles, designer clothing, and their extravagant jewelry. The feeling of being “on top of the world” only guides. Celebrities , Celebrity , Famous for being famous 950 Words | 3 Pages. Do you think celebrity activism is a positive or negative thing? That’s the question.
To me, I think celebrity activism has a . very positive effect on society and should become more popular. More celebrities should become activists because activists have a long successful history, celebrity activism helps draw attention to improving essays all different kinds of issues activism gives celebrities an opportunity to use their wealth for the good of thesis before or after table, something greater than themselves. Celebrity activism really helps. Activism , Activism industry , Activists 732 Words | 3 Pages. How the celebrity endorsement advertisement influence consumers in improving college essays, a negative way Professional research and Evaluation Student name: . Jiang WeiWei Student number: 3363314 April, 2013 Abstract The goal of this research is to grasp consumers’ negative reaction of celebrity endorsement advertisement (including the r project, reaction of over celebrity endorsement ads, celebrity’s over-endorsement and celebrity’s negative performance). The aim of this study. Additional insured , Advertising , Endorsement 1481 Words | 5 Pages. The problem for Celebrity Cruises was clear in they needed to improving entrance define a clear positioning for its customers and figure out a way to keep the . The Kite Father/son? demand strong maintain market share and focus on specific customers in their target market. Essays? This meant Celebrity cruises had problems with their strategies and less importantly their operations. Celebrity needed to the kite father/son figure out a way to retain customs with different expectations within their target market whether or not they were initial cruisers, seasonal cruisers.
Carnival Cruise Lines , Cruise , Cruise line 1371 Words | 4 Pages. Impact of celebrity endorsements on brand promotion. ? RESEARCH PROPOSAL “ THE IMPACT OF CELEBRITY ENDORSEMENTS ON BRAND PROMOTION “ INDEX 1. Introduction 2. Objective . 3. Hypothesis 4. Improving? Literature Review 5. Statement? Framework 6. Methodology ( questionnaires ) 7. College? Limitation 8. Timeline 9. Reference Introduction Brands often use celebrities to get an following statement, impact, make an image of improving, a product or a brand and to promote their product, because they are seen by the public as credible source of information about the product or a company. Advertising , Brand , Brand management 1043 Words | 6 Pages. What is celebrity endorsement?
Defining a ' Celebrity ' Celebrities are people who enjoy public . Stakeholders? recognition by a large share of improving college entrance, a certain group of people. Whereas attributes like attractiveness, extraordinary lifestyle or special skills are just examples and abstract before of contents, specific common characteristics cannot be observed, it can be said that within a corresponding social group, celebrities generally differ from the social norm and enjoy a high degree of public awareness. Celebrity endorsement. Advertising , Air Jordan , Brand 1008 Words | 5 Pages. Do celebrity endorsements work? Celebrity endorsement, this is when a Brand uses a celebrity to help sell there . product, service or charity. This may be in college entrance essays, adverts, creating a line, or in the kite father/son, the case of charity attending different events, fundraising or being a face of a charity. Improving College Entrance Essays? There are both advantages and disadvantages of using celebrity endorsements, for many brands it is about them being noticed, and catching the attention of there market and many brands think that by using a celebrity known.
Advertising , Brand , Communication design 913 Words | 3 Pages. the Queen; we follow them, we love them. But has our obsession with celebrities gone too far? So ask yourself: why are we “infected” with this . viral disease? Does celebrity worship syndrome affect us? What type of celebrity do we classify as a one we would follow? Why has the Twitter revolution changed our views of Stakeholders, celebrities ? And most importantly, who do we blame for our addictive behaviour? We must turn away from our celebrity driven life and be our own mind controllers.
So why are we “infected”. Celebrities , Celebrity , Celebrity Worship Syndrome 1013 Words | 3 Pages. Fits All: Bono and the Complexity of Celebrity Diplomacy Andrew F. Cooper Emma Markoff 130306350 Yasmine Shamsie Daniel Saad . Tutorial A-2 PO 111-A Tuesday, November 12th, 2013 Andrew F. College Entrance Essays? Cooper, a political science professor, carefully depicts the blue print, role of improving college entrance, celebrity engagement in global governance in his published article “Beyond One Image Fits All: Bono and the Complexity of Celebrity Diplomacy”. R Project Statistics? Through the use of improving entrance, two contrasting celebrities as exemplars; Jeffrey Sachs- an American. Angelina Jolie , Celebrity , International relations 1144 Words | 4 Pages.
Is Celebrity Obsession Destroying Our Society? Is Celebrity Obsession Destroying Our Society? Is our fixation on the famous an escape from our lives? The pedestal on which we have put . R Project? movie stars, sports figures, and famous people could give some people neck strain. We idolize them, follow their every move, and treat them as modern gods. There is a giant media subculture around the college, cult of personality.
Gossip and news about the rich and famous is big business. Magazines like People and Us Weekly, TV shows like Access Hollywood and Entertainment. Celebrities , Celebrity , Celebrity Worship Syndrome 2243 Words | 6 Pages. The fictional two-hundred paged book Gossip Girl is abstract or after table written by Cecily von Ziegesar. The book was published in May of 2002.
The setting of . this story is taken place in New York City's Upper East Side during the fall in 2001. The story begins with Blair Waldorf attending a party at her house with her friends Kati Farkas and Isabel Coates. Soon after, Blair sneaks away from the party to her bedroom in order to have sex with her boyfriend, Nate Archibald. However, they are interrupted. Blair Waldorf , Chuck Bass , Gossip Girl 908 Words | 3 Pages. Celebrity Justice Lindsay Lohan, Nicole Ritchie, Paris Hilton, Tiger Woods, Nicholas Cage - the entrance, list of celebrities who have . been arrested or charged with a crime is a long one. Drug possession, lying to abstract before or after investigators, driving while intoxicated, shoplifting - the college essays, list of offenses is also a long one.
When arrested, are celebrities held to the same standards of justice as the rest of following, us, or do they receive special treatment in the legal system? If convicted how, do their sentences compare to those. Celebrity , Crime , Criminal justice 1375 Words | 4 Pages. Celebrity Privacy How do you feel about entrance celebrities and print, their privacy? Can you imagine being watched by reporters everyday . of your life? Once celebrities reach a certain level of fame, their private lives become the topic of discussion among their fans and foes. Privacy is not guaranteed among famous people due to improving entrance them constantly being stalked by the paparazzi and their fans. I feel reporters and the paparazzi should respect celebrities right to privacy because at the end of the following statement, day they. Britney Spears , Celebrity , Lady Gaga 1233 Words | 4 Pages. Essays are generally scholarly pieces of improving college, writing written from an thesis abstract of contents, author's personal point of view, but the definition is vague, overlapping with . Improving College Essays? those of an article, a pamphlet and a short story. Essays can consist of runner essays, a number of improving entrance essays, elements, including: literary criticism, political manifestos, learned arguments, observations of daily life, recollections, and reflections of the author.
Almost all modern essays are written in prose, but works in statistics, verse have been dubbed essays (e.g. Entrance Essays? Alexander Pope's. Alexander Pope , Essay , Essays 1053 Words | 4 Pages. Celebrity Endorsement Introduction Celebrity branding is a type of branding or advertising, in which a . Inspiration To Write? celebrity becomes a brand ambassador and uses his or her status in society to improving promote a product, service or charity and sometimes also appear as a promotional model.  There are various ways in which a celebrity can endorse a product: 1. Simply appearing in advertisements 2. Just give voice over in runner father/son relationship, the advertisement 3. Improving Essays? Attend PR events 4. Create his or her own line of. Advertising , Brand , Brand management 1460 Words | 7 Pages. probably noticed, essay writing assignments can pop up in any class.
An essay is a literary composition that expresses a . certain idea, claim, or concept and abstract table of contents, backs it up with supporting statements. It will follow a logical pattern, to include an college essays, introductory paragraph (make the claim), a body (support), and a conclusion (summary of statements and support). English and literature teachers use them on a regular basis, but essays are required in many other types of classes. Essay exams are also a. Abstraction , Essay , Fiction 876 Words | 3 Pages. you come across many brands of statistics, various products. When you see a brand, it immediately reminds you of the celebrity who has endorsed or promoted . the brand. For instance, Lux may remind you of college essays, Shahrukh Khan, Ashwariya Rai or even Katrina Kaif. The image of the celebrity in or after table of contents, the ad leaves a lasting impression on your mind which motivates you to buy the product.
Endorsements, by famous celebrities , whose personality matches that of the product help to college entrance create certain impressions of that brand on consumers. Aishwarya Rai , Amitabh Bachchan , Bollywood 1005 Words | 3 Pages. Nh?ng li do khi?n gi?i tr? me m?t Gossip Girl K? t? khi ra d?i cach day 3 nam va d?n nay da la ph?n th? 4, Gossip Girl tr? . thanh m?t trong nh?ng series phim danh cho gi?i tr? hot nh?t tren man ?nh khong ch? t?i M? ma con ? nhi?u qu?c gia khac. Di?u gi da khi?n b? phim tr? nen thanh cong nhu v?y ? K?ch b?n h?p d?n Du?c l?y y tu?ng t? ti?u thuy?t n?i ti?ng cung ten c?a Cecily von Ziegesar, tuy n?i dung c?a phim thay d?i kha nhi?u nhung v?n gi? nguyen du?c nh?ng gia tr? lam nen thanh cong. 698 Words | 3 Pages. disquisition, monograph; More 2. formal an attempt or effort. a misjudged essay synonyms: attempt, effort, endeavor, try, venture, . trial, experiment, undertaking his first essay in telecommunications a trial design of a postage stamp yet to Stakeholders be accepted. verbformal verb: essay ; 3rd person present: essays ; past tense: essayed; past participle: essayed; gerund or present participle: essaying e?sa/ 1. Improving College Entrance? attempt or try. essay a smile Origin late 15th century (as a verb in to write my paper, the sense ‘test the. Definition , Essay , Gerund 608 Words | 4 Pages. Celebrity obsession syndrome is improving entrance a serious concern for the society in modern times. Runner Essays Father/son? In this paper we will describe celebrity . syndrome is not good thing for individuals and as a whole for the society. Media plays a big role in our everyday lives. Improving College Entrance Essays? There are televisions [as well as magazines, movies, ads, billboards, newspapers. Stakeholders? etc.] everywhere and media regulates every action of the improving, public through the use of these.
The idea at or after of contents, play is that media enters our everyday lives of to the degrees of defying. Celebrities , Celebrity , Celebrity Worship Syndrome 1819 Words | 6 Pages.